Bis(μ-nitrito-κ2O:O)bis[bis(1-methyl-1H-imidazole-κN3)(nitrito-κO)copper(II)]
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چکیده
منابع مشابه
Bis(μ-nitrito-κ2 O:O)bis[bis(1-methyl-1H-imidazole-κN 3)(nitrito-κO)copper(II)]
In the binuclear title compound, [Cu(2)(NO(2))(4)(C(4)H(6)N(2))(4)], centro-symmetric-ally related complex mol-ecules are linked via weak Cu-O inter-actions, forming dimeric units. The Cu(II) atom displays an elongated square-pyramidal CuN(2)O(3) coordination geometry with a slight tetra-hedral distortion of the basal plane [maximum deviation = 0.249 (2) Å]. The dihedral angle formed by the imi...
متن کامل1-Methyl-5-nitro-1H-imidazole
In the title compound, C(4)H(5)N(3)O(2), the nitro group is twisted with respect to the imidazole ring by a dihedral angle of 5.60 (2)°. Weak inter-molecular C-H⋯O and C-H⋯N hydrogen bonding is present in the crystal structure.
متن کامل1-Methyl-4,5-dinitro-1H-imidazole
In the title compound, C(4)H(4)N(4)O(4), the two nitro groups are twisted with respect to the imidazole plane, making dihedral angles of 24.2 (3) and 33.4 (4)°. In the crystal structure, the mol-ecules are linked through non-classical inter-molecular C-H⋯O hydrogen bonds.
متن کاملDi-μ-nitrito-κ4 O:O-bis[bis(1-ethyl-1H-imidazole-κN 3)(nitrito-κO)copper(II)]
In the structure of the title compound, [Cu(2)(NO(2))(4)(C(5)H(8)N(2))(4)], the asymmetric unit consists of two moieties containing one Cu ion, two nitrite ions and two 1-ethyl-1H-imidazole mol-ecules associated via weak Cu-O inter-actions. Each Cu(II) atom displays an elongted square-pyramidal CuN(2)O(3) coordination geometry with a slight tetra-hedral distortion in the basal plane. The dimeri...
متن کاملBis(2-ethyl-1H-imidazole-κN 3)bis(nitrito-κ2 O,O′)copper(II) dihydrate
In the title compound, [Cu(NO(2))(2)(C(5)H(8)N(2))]·2H(2)O, the Cu(2+) ion exhibits site symmetry 2 and is hexacoordinated by four O atoms from two nitrite ions and two N atoms from two 2-ethyl-1H-imidazole mol-ecules. A free water mol-ecule assists in forming a three-dimensional network holding together the complexes via O-H⋯N, O-H⋯O and N-H⋯O hydrogen bonds.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812009804